Environmental Diagnosis of Risk Areas Related to Gas Stations

Studies were carried out on the localization and mapping of gas stations in the urban area of São Carlos city, for an environmental diagnosis related to soil, surface water and underground water contamination resulting from likely leaking in fuel underground storage tanks. Considering that a provision of legal restriction makes it possible that most of public areas are not located in gas station areas of potential risk, these information are useful for the development of programs designed to reduce risks to public safety and health and of the soil, surface water and underground water contamination. Key-words: Gas station; undergrounded storage tank; high risk area * Author for correspondence INTRODUCTION One of the major contamination sources of the soil, air, underground and surface water has been related to liquid fuel tank leakings, processed chemical products, toxic chemical products and diluted rejects. As of 1985, fuel underground storage tanks became a priority in the United States, leading to the regulation, by the Environmental Protection Agency (EPA) of prevention, detection and fixing of leaking in the tanks, as well as to the creation of a specific agency (Office of Underground Storage Tanks) to supervise these aspects (EPA, 1984; 1985a;b). Fuel underground storage tanks in the United States amount to approximately three million units, and according to conservative estimates, some 10% of them can be leaking (Canter et al., 1988). Sealing tests in fuel underground storage tanks of São Paulo city show that approximately 80% of them have some type of leaking in the suction line or in the storage tank itself (Oliveira, 1992). The most common causes for leaking are related to structural deficiencies, mainly a result of inappropriate installation of fuel storage tanks and corrosion of their internal and/or external lining (Pearson and Oudjik, 1993). In Brazil, corrosion is considered the main cause of leaking, since most of fuel storage tanks do not have a protective external lining and have been in use for more than 20 years (Oliveira, 1992). Most of the fuel underground storage tanks store petroleum or its by-products represented by aliphatic or aromatic hydrocarbons. Gasoline, for example, is composed of more than 70 hydrocarbons, including aliphatic hydrocarbons, such as pentane and butane, and aromatic hydrocarbons, such as benzene, toluene and xylene, usually categorized as BTX substances. In leaking conditions, these by-products can contaminate the soil and underground water, or, when in the volatile form in the atmosphere, they can be a risk to public safety and health (Bruell and Hoag, 1984). Fuel underground storage tanks Moschini, L. E. et al. Brazilian Archives of Biology and Technology 658 represent a potential source of contamination, in which the level and type of risk depend on the way the fuel is managed, as well as on the landscape structural characteristics (soil type, river network, etc) of the urban area where they are. Informations based on the georeferenced mapping and overlaying of gas stations in relation to social and hydro-geological characteristics of the urban landscape are of great importance for the development of programs designed to reduce risks to health and public safety and risks of soil and water contamination. This paper provides an environmental diagnosis related to São Carlos’urban areas running potential risks of having their soil, surface water and underground water contaminated as a result of likely leaking of fuel underground storage tanks. MATERIAL AND METHODS The São Carlos county is located in the central region of the São Paulo State, Brazil, between the coordinates 4455’ and 4750’W and 2100’ and 2230’S (Fig. 1). It covers an area of approximately 416.81 km, of which about 52 km correspond to a urban area, with a low green area index (Oliveira, 1996). São Carlos’ climate can be classified as subtropical humid (Nimer, 1972), with hot and humid summer seasons and dry winter seasons. São Carlos has a humid and hyperthermal climate in the areas where the altitude is below 1,000 meters, whereas in regions above 1,000 meters it has a thermal climate (Oliveira, 1996). The mean values of precipitation and relative humidity are 1512 mm and 66%, respectively. The region’s hydric balance reveals that the groundwater level represents, on average, from 1/4 to 1/3 of monthly precipitation, what characterizes it as a recharge area of the Botucatu aquifer (Mattos, 1984). The municipality of São Carlos is within the seventh ecological region of the State of São Paulo, on “basaltic cuestas” with altitudes from 800 to 900 meters (Troppmair, 1975). The main streams draining the urban area are Monjolinho, Mineirinho, Gregório, Tijuco, Medeiros, Lazarini, Água Quente and Água Fria. The most of them has theirs springs within the municipality area. The Monjolinho stream limits topographically, on the cuesta reverse, the region where most of the urban area is located (Gonçalves, 1986). Districts that have been growing recently, such as Cidade Aracy and Santa Felícia, are in the right watershed of Monjolinho stream (Oliveira, 1996). Data collection about gas stations included the following information: name, address and georeferenced location in the urban area; flag; number of gas pumps referring to each type of stored fuel; period during which they were on operation in 2003; total number of underground storage tanks and total storage capacity per type of fuel in 2003. Gas stations were grouped in two categories, based on how they operate (http://www.anp.gov.br): commercial gas stations which only buy fuel from a wholesale distributor and sell it on a retail basis, and restricted gas stations for the private use of specific companies or institutions. The identification and environmental diagnosis of the areas presenting potential risks of soil, surface water and underground water contamination were obtained by overlaying the georeferenced gas stations thematic chart on the following urban area thematic charts: river basins; pedology; population density (Oliveira et al., 1999); high risk areas of 100 m (Resolution CONAMA 273, of 29/Nov/2000) with reference to the river network and to 19 water pumping stations supplying urban and private consumers, and high risks areas of 150 m (Municipal Law 13217 of 01/Oct./2003) as a minimum distance of gas stations from a total of 93 public usage areas. Such kind of areas included state public schools (29), local public schools (28), private schools (17), health care centers (08), day care centers (8) and hospitals (03). Environmental Diagnosis of Risk Areas Related to Gas Stations Brazilian Archives of Biology and Technology 659 Figure 1 Geographical location of the São Carlos county, São Paulo State. The urban areas thematic charts (river basins, river network, pedology, urban roadnet and population density) were obtained based on the charts from the Geographic and Cartographic Institute for the São Carlos city and on the utilization of the GISIDRISI software. RESULTS AND DISCUSSION General information regarding gas stations such as name, address, and other aspects, as well as the landscape structural elements of the urban area where they are located, are available in a database (http://www.lapa.ufscar.br). There has been a significant increase in the number of gas stations in São Carlos city for the last 18 years. In 1985, there were only 25 gas stations (Gonçalves, 1991). In 2003, these gas stations were 64 in the urban area, 58 of which referred to dealers with commercial purposes and 6 gas stations restricted to companies and/or institutions. The total number of gas stations covered an area of 52 km, totaling 291 underground storage tanks, 16 of which were related to restricted gas stations. This survey did not take into account fuel aerial storage tanks confined to some private companies. About 40% of gas station have been operating for more than 15 years; 12% of them, from 10 to 15 years, and approximately 48% for less than 10 years (Fig. 2). It is important to note that the period during which a gas station operates is not the only factor for the analysis of the potential risk of fuel leaking. The age of underground storage tanks should also be considered, particularly because older gas stations could have replaced their underground storage tanks, and newer gas stations can have new facilities but old underground storage tanks. Approximately 44.5% of underground storage tanks in São Carlos city are in gas stations that have been operating for more than 15 years (Fig. 2), indicating potential Moschini, L. E. et al. Brazilian Archives of Biology and Technology 660 leaking risks and likely contamination of soil and underground water. The legislation establishes that underground storage tanks shall be replaced within a 5-year period at the most (Resolution CONAMA 319, of 04/Dec/2002). The Europe and the United States experiences showed that gasoline underground storage tanks corroded and leak for an average period of 20 years after installed, in many cases, in 15 years, if they did not have a cathodic protection. It has been evidenced that 71% of gasoline underground storage tanks leak 10 years after they were installed, whereas some 46%, in 15 years, compared to 53% of leaking in pipeline that took place 10 years after installation, and 77%, in 15 years (Oliveira, 1992). Little has been published about gasoline leakage in São Paulo. Virtually no data are available about São Carlos. This happens because environmental agencies are notified only in exceptional situations of visible fuel leaking that represents risk to the public safety and health. Figure 2 Total number of gas stations (GS) and of underground storage tanks (UST) of São Carlos city as a function of operation time (2003). According to data from CETESB of May/2002 out of 255 notifications about contaminated areas in the State of São Paulo, 60 referred to gasoline leakage in gas stations (http://www.cetesb.sp.gov.br). In case of accidents or leaking that may be a risk to the society, the responsible party is the owner or the person in charge of the establishment. The fuel supplier shall help as regards measures to control the emergency situation and to solve problems in the impacted area, according to the requirements established by the environmental agency. In most cases, the existence of leakage is reported to the owner by the distributor, and sometimes the local authorities are not informed about the fact. The total fuel storage capacity in the city of São Carlos in 2003 was estimated at 4,595,000 liters, 1,230,000 liters of which referring to fuel alcohol, 1,595,000 liters to conventional gasoline, 595,000 liters to premium gasoline, 1,100,000 liters to diesel, 60,000 liters to premium diesel and 15,000 liters to kerosene, distributed among 64 gas stations and 291 underground storage tanks (Table 1). Of the total, approximately 6% had a capacity of more than 30,000 liters. The concern about the 30,000 liter-tank limit (Item h, Article 6 of Municipal Law 12349 of 04/Jan/2000) is important since it can reduce the risks associated to leaking volumes and to the types of fuels stored. Commercial and restricted gas stations were Environmental Diagnosis of Risk Areas Related to Gas Stations Brazilian Archives of Biology and Technology 661 distributed only in 6 river basins: Monjolinho Nascente Urbana; Mineirinho; Tijuco; Gregório; Medeiros e Água Quente (Table 1). The Gregório river basin showed the higher potential of soil and underground water contamination risk as a result of likely fuel leakage from underground storage tanks and from its pipelines. It comprised 30 gas stations, 146 underground storage tanks, with a total volume of 2,315,000 liters of fuel (Table 1). The risk was higher considering that about 60% of the gas stations in Gregório river basin was operating for more than 15 years, and also due to the geological characteristics of the soils (soil permeability and level of corrosion) where they were located. Although they have not been subject of study, the environmental diagnosis of risks associated to the existing and potential leaking in underground storage tanks is highly dependent on the way fuels behave in different types of soils, which is influenced by the physical and chemical properties of liquid fuels (density, viscosity, solubility and vapor pressure) and by the characteristics of the soils through which these fuels migrate (Guiguer, 1996). Table 1. Total number of commercial gas stations (CGS), restricted gas stations (RGS), underground storage tanks (UST), and of volumes of different stored fuel by river basin delimited for São Carlos city in 2003. river basins number of CGS number of RGS number of UST alcohol (L) gasoline (L) premium gasoline (L) diesel (L) premium diesel (L) kerosene (L) total volume (L) A – Monjolinho Nascente